


|
Production Methods |
The compound results from condensation of butanediol with epichlorohydrin followed by dehydrochlorination with caustic. |
|
General Description |
Clear pale yellow liquid. |
|
Air & Water Reactions |
Hygroscopic. Water soluble |
|
Reactivity Profile |
1,4-Butanediol diglycidyl ether reacts with acids. |
|
Fire Hazard |
1,4-Butanediol diglycidyl ether is combustible. |
|
Flammability and Explosibility |
Nonflammable |
|
Contact allergens |
This substance is a reactive diluent in epoxy resins |
|
Carcinogenicity |
A2 year dermal cancer bioassay was conducted in CF1 mice at doses of 0%, 0.05%, and 0.2% in acetone . Treatment did not adversely affect survival, did not increase the incidence of skin tumors, and did not result in significant skin irritation. There were no statistically significant increases in incidence of any systemic tumors, except for lymphatic tumors in females. Because there was a high background incidence of this tumor type in CF1 mice used in the testing laboratory , there was no clear evidence of 1,4-BDDGE-induced carcinogenicity. |
InChI:InChI=1/C6H10O3.C4H10O2/c1(5-3-8-5)7-2-6-4-9-6;1-2-3-4(5)6/h5-6H,1-4H2;4-6H,2-3H2,1H3
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Butane-1,4-diol
epichlorohydrin
1,4-Butanediol diglycidyl ether
| Conditions | Yield |
|---|---|
|
With
tetrabutyl-ammonium chloride; water; sodium hydroxide;
at 40 ℃;
for 0.75h;
|
89% |
|
With
sodium hydroxide; tetrabutyl-ammonium chloride;
In
water;
at 40 ℃;
for 0.75h;
|
71.3% |
|
With
boron trifluoride; benzene;
behandeln des Reaktionsprodukts mit wss. Kalilauge;
|
|
|
With
tetrabutyl-ammonium chloride; sodium hydroxide;
In
water;
at 40 ℃;
for 2h;
|
1,4-Butanediol diglycidyl ether
| Conditions | Yield |
|---|---|
|
|
Butane-1,4-diol
epichlorohydrin
3,3'-di-p-tolyl-5,5'-(2,7-dioxa-octane-1,8-diyl)-bis-oxazolidin-2-one
1,4-Bis-<2-hydroxy-3-chlor-propoxy-butan>
C32H49ClN2O11
racemic 1,4-butanediol diglycidyl ether