


|
Definition |
ChEBI: A benzothiadiazole that is the S-methyl thioester derivative of acibenzolar. It is used as a fungicide and plant activator on a variety of crops, including cotton, chili peppers, lettuce, onions, spinach, tobacco, and tomatoes. |
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Metabolic pathway |
Very little information on the fate of CGA245704 has been published. It is readily degraded in soil and plants and it is rapidly eliminated from animals. A partial metabolic pathway is shown in Scheme 1. |
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Degradation |
CGA245704 is a stable substance and it is very stable in solution other than at high pH values. Its DT50 values (20 °C) at pH 5, 7 and 9 were 3.8 years, 23 weeks and 19 hours, respectively (PM). Hydrolysis of the thioester link and ring opening would be anticipated. |
InChI:InChI=1/C8H6N2OS2/c1-12-8(11)5-3-2-4-6-7(5)13-10-9-6/h2-4H,1H3
Plant activators are a novel kind of agr...
The present invention relates to novel a...
The present invention relates to novel a...
Salicylic acid (SA) and methyl jasmonate...
Lawessons reagent
benzo-1,2,3-thiadiazole-7-thiomethyl ester
S-methyl-benzo[1,2,3]thiadiazole-7-carbothioate
| Conditions | Yield |
|---|---|
|
In
5,5-dimethyl-1,3-cyclohexadiene;
|
benzo[d][1,2,3]thiadiazole-7-carboxylic acid
S-methyl-benzo[1,2,3]thiadiazole-7-carbothioate
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 2 steps
1: SOCl2 / 8 h / 90 °C
2: 0.12 g / CH2Cl2 / 5 h / 20 °C
With
thionyl chloride;
In
dichloromethane;
|
|
|
Multi-step reaction with 2 steps
1: SOCl2
With
thionyl chloride;
1: Substitution / 2: Esterification;
|
|
|
Multi-step reaction with 2 steps
1: thionyl chloride
2: sodium hydroxide
With
thionyl chloride; sodium hydroxide;
|
methylthiol
benzothiadiazole-7-carboxylic acid chloride
sodium thiomethoxide
benzo[d][1,2,3]thiadiazole-7-carboxylic acid